
%0 Journal Article
%A Khalafy, Jabbar 
%A Prager, Rolf H 
%T Flash Vacuum Pyrolysis of Some <emph type="2">N</emph>-Benzylbenzotriazoles and <emph type="2">N</emph>-Benzylbenzisoxazolones
%J Australian Journal of Chemistry
%D 1998/10/07
%V 51
%N 10
%P 925-930
%K 
%R https://doi.org/10.1071/C98065
%U https://www.publish.csiro.au/paper/C98065 
%X The flash vacuum pyrolysis products of 2-(benzotriazol-1-ylmethyl)benzonitrile, methyl 2-(benzotriazol-1-ylmethyl)benzoate and the corresponding benzisoxazolones have been characterized. The benzotriazoles lose nitrogen to give diradicals which undergo intramolecular hydrogen-atom transfer or cyclization, while the benzisoxazolones rearrange initially to the corresponding benzaldehyde N-(2-carboxyphenyl)imines which undergo subsequent intramolecular addition reactions. 
