
TY  - JOUR
A1  - Lopes, Luiz G. F. 
A1  - Gomes, Maria G. 
A1  - Borges, Simone S. S. 
A1  - Franco, Douglas W. 
T1  - Correlation Between the Lever Parameter and Electronic Properties of Nitrosyl Ruthenium(II) Complexes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1998
VL  - 51
IS  - 9
SP  - 865
EP  - 866
KW  - 
UR  - https://doi.org/10.1071/C97216 
N2  - The Lever parameter (EL), for a series of ruthenium nitrosyl complexes of the type &#91;Ru(NH3)4NOL&#93; n+, where ligand L = nicotinamide (nic), isonicotinamide (isn), pyrazine (pz), pyridine (py), imidazole (imN), L-histidine (L-hist), NH3, trimethyl phosphite &#91;P(OMe)3&#93; and triethyl phosphite &#91;P(OEt)3&#93;, is correlated to Epc1 (the potential for the reduction RuNO++e- &rarr; RuNO 0) and v(NO) data. A correlation is observed between &sum;EL and Epc1, and between &sum;EL and v(NO), since these parameters are dependent on electronic characteristics of the nitrosyl group. For &sum;EL v. Epc1, the slope, SL, and intercept, IL, of the linear correlation are related to interligand coupling through the metal centre and to the extent of the Ru &rarr; NO back bonding. 
ER  -

