
%0 Journal Article
%A Astley, Timothy 
%A Hitchman, Michael A. 
%A Skelton, Brian W. 
%A White, Allan H. 
%T Structure, Electronic Spectrum and Angular-Overlap Bonding Parameters of Bis[bis(pyrazol-1-yl)(2-thienyl)-methane](nitrato-<emph type="2">O</emph>,<emph type="2">O</emph>&#8242;)nickel(II) Nitrate
%J Australian Journal of Chemistry
%D 1997/04/01
%V 50
%N 2
%P 145-148
%K 
%R https://doi.org/10.1071/C96192
%U https://www.publish.csiro.au/paper/C96192 
%X The crystal structure of the complex &#91;Ni(pz2thCH)2(O(O&#8242;)NO&#8242;&#8242;)&#93; NO3 has been determined by X-ray diffraction, where pz and th represent the pyrazolyl and thienyl groups of a potentially tripodal ligand. The thienyl groups are not bound to the metal, which is coordinated to four pyrazolyl groups and a chelating nitrate ion. The electronic &#8216;d&#8211;d&#8217; transition energies are interpreted in terms of angular-overlap bonding parameters which agree well with those reported for other similar complexes. 
