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The Impact of Water on the Lateral Nanostructure of a Deep Eutectic Solvent–Solid Interface

Aaron Elbourne https://orcid.org/0000-0002-4472-4372 A F G , Quinn A. Besford B F , Nastaran Meftahi C , Russell J. Crawford A , Torben Daeneke D , Tamar L. Greaves A , Christopher F. McConville A E , Gary Bryant A , Saffron J. Bryant A G and Andrew J. Christofferson A G
+ Author Affiliations
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A School of Science, RMIT University, Melbourne, Vic. 3000, Australia.

B Leibniz Institute for Polymer Research, Dresden 01069, Germany.

C ARC Centre of Excellence in Exciton Science, School of Science, RMIT University, Melbourne, Vic. 3001, Australia.

D School of Engineering, RMIT University, Melbourne, Vic. 3000, Australia.

E Institute for Frontier Materials, Deakin University, Geelong, Vic. 3216, Australia.

F Co-first authors.

G Corresponding authors. Email: aaron.elbourne@rmit.edu.au; saffron.bryant@rmit.edu.au; andrew.christofferson@rmit.edu.au




Dr Aaron Elbourne is a post-doctoral research fellow within the School of Science at RMIT University. He currently holds a Jack Brockhoff Foundation Early Career Medical Research Fellowship and is a leader within RMIT’s ECR network. He obtained his Ph.D. in chemistry in 2017 from The University of Newcastle, Australia, under the supervision of Professor Erica J. Wanless. He began his post-doctoral fellowship in February of 2017. His early research focused on molecular-resolution atomic force microscopy (AFM) imaging, with an emphasis on fundamental ion adsorption at the solid-liquid interface. His current research has ‘shifted gears’ to focus on anti-microbial surface and particle technologies and bio-interfacial studies. He has a passion for research with real-world applications and for industrial translation. More broadly, he is interested in developing next-generation vaccine technologies, antimicrobial technologies, anti-cancer antibodies, and new methods for combating antibiotic resistance.



Dr Saffron Bryant is a research fellow at RMIT University where she is investigating novel methods of cryopreservation. Saffron has experience in a variety of scientific disciplines, having gained her bachelor’s degree in biomedical science, her Ph.D. in chemistry, and currently working in a physics department. She completed her Ph.D. in 2017 under the supervision of Professor Gregory Warr where she examined amphiphile self-assembly in ionic liquids and deep eutectic solvents. She is especially interested in applying her experience with neoteric solvents to health-related and real-world problems.



Dr Andrew Christofferson received a bachelor’s degree in chemistry from Montana State University, USA, and a Ph.D. in chemistry with a focus on computational chemistry from the University of Birmingham, UK. During his Ph.D. studies, he determined the reaction mechanism for the reduction of the chemotherapy prodrug CB1954 by the enzyme NfsB. His post-doctoral work at the National Institute of Biological Sciences, China, resulted in new models for selenium-modified DNA, and an explanation for the experimentally observed differences in DNA melting points with various modified base pairings. He also received a grant from the National Natural Science Foundation of China for design and applications of a reactive force field for ambient-temperature proton transfer reactions. In his current position as a research fellow at RMIT University, he uses molecular dynamics simulations and quantum chemical calculations along with experimental X-ray diffraction data to determine atomistic models of self-assembled materials, polymers, biomaterial interactions, liquid metals, ionic liquids, and deep eutectic solvents.

Australian Journal of Chemistry 75(2) 111-125 https://doi.org/10.1071/CH21078
Submitted: 25 March 2021  Accepted: 5 June 2021   Published: 6 July 2021



7 articles found in Crossref database.

Encyclopedia of Solid-Liquid Interfaces (2024)
Elbourne Aaron, Awad Miyah N., Meredith Leon, Christofferson Andrew J., Greaves Tamar L., Bryant Gary, Bryant Saffron J.
Behavior of Citrate-Capped Ultrasmall Gold Nanoparticles on a Supported Lipid Bilayer Interface at Atomic Resolution
Kariuki Rashad, Penman Rowan, Bryant Saffron J., Orrell-Trigg Rebecca, Meftahi Nastaran, Crawford Russell J., McConville Chris F., Bryant Gary, Voïtchovsky Kislon, Conn Charlotte E., Christofferson Andrew J., Elbourne Aaron
ACS Nano. 2022 16(10). p.17179
Manipulating meso-scale solvent structure from Pd nanoparticle deposits in deep eutectic solvents
Hammons Joshua A., Besford Quinn A., Ilavsky Jan, Christofferson Andrew J.
The Journal of Chemical Physics. 2021 155(7).
Trace Water Changes Metal Ion Speciation in Deep Eutectic Solvents: Ce3+ Solvation and Nanoscale Water Clustering in Choline Chloride–Urea–Water Mixtures
Hammond Oliver S., Bathke Elly K., Bowron Daniel T., Edler Karen J.
Inorganic Chemistry. 2023 62(44). p.18069
Interfacial Nanostructure and Hydrogen Bond Networks of Choline Chloride and Glycerol Mixtures Probed with X-ray and Vibrational Spectroscopies
Kim Pyeongeun, Weeraratna Chaya, Nemšák Slavomír, Dias Nureshan, Lemmens Alexander K., Wilson Kevin R., Ahmed Musahid
The Journal of Physical Chemistry Letters. 2024 15(11). p.3002
Mapping the Three‐Dimensional Nanostructure of the Ionic Liquid–Solid Interface Using Atomic Force Microscopy and Molecular Dynamics Simulations
Elbourne Aaron, Dupont Madeleine, Kariuki Rashad, Meftahi Nastaran, Daeneke Torben, Greaves Tamar L., McConville Christopher F., Bryant Gary, Bryant Saffron J., Besford Quinn A., Christofferson Andrew J.
Advanced Materials Interfaces. 2023 10(7).
Physico-chemical characterisation of glycerol- and ethylene glycol-based deep eutectic solvents
Meredith Leon, Elbourne Aaron, Greaves Tamar L., Bryant Gary, Bryant Saffron J.
Journal of Molecular Liquids. 2024 394 p.123777

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