Register      Login
Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science

Articles citing this paper

On the Origins of Nitroxide Mediated Polymerization (NMP) and Reversible Addition–Fragmentation Chain Transfer (RAFT)*

Ezio Rizzardo A C and David H. Solomon B C
+ Author Affiliations
- Author Affiliations

A CSIRO Materials Science and Engineering, Clayton South, Melbourne, Vic. 3169, Australia.

B Department of Chemical & Biomolecular Engineering, The University of Melbourne, Parkville, Melbourne, Vic. 3010, Australia.

C Corresponding authors. Email: ezio.rizzardo@csiro.au; davids@unimelb.edu.au




Ezio Rizzardo (right) graduated with first class honours in applied organic chemistry from the University of New South Wales and was awarded a Ph.D. in organic chemistry by the University of Sydney in 1969 for his studies on the photochemistry of organic nitro compounds. He joined David Solomon’s group at CSIRO in 1976 after postdoctoral work on the synthesis of biologically active compounds with Richard Turner at Rice University (Houston), Sir Derek Barton at RIMAC (Boston), and Arthur Birch at the ANU (Canberra). His research at CSIRO has focused on the development of methods for understanding and controlling polymerization processes. He is the co-author of some 200 journal papers, which to date have received over 13000 citations, and co-inventor on 44 worldwide patents. He is a Fellow of the Royal Society of London, the Australian Academy of Science and the Australian Academy of Technological Sciences and Engineering, and the recipient of the Australian Polymer Medal, the CSIRO Chairman’s Gold Medal and the Australian Government’s Centenary Medal for contributions to society and polymer science. David Solomon (left) graduated from the University of New South Wales with a Ph.D. in 1959 and a D.Sc. in 1968; he also holds a Diploma in Chemistry from Sydney Technical College (1950). During his studies, he worked for Dulux and this is where his interest in the chemistry of radical polymerization began. He was seconded to work at ICI Paints Division in 1959 and returned to Dulux to set up their polymer research group. In 1963, he joined CSIRO and set up the polymer research section. He recruited Ezio into this group and together they developed techniques to better understand radical chemistry and eventually living radical systems. David was also the principal inventor of the world’s first polymer banknote. He was President of the Royal Australian Chemical Institute (RACI) from 1979 to 1980. He is a Fellow of the Royal Society of London, the Australian Academy of Science, the Australian Academy of Technological Sciences and Engineering (Foundation Fellow), the RACI and the Institute of Chemical Engineers. He has received numerous awards, including Member of the Order of Australia, D.App.Sc. (Honoris Causa) (University of Melbourne), and is the sole recipient of Australia’s Bicentennial Science Achievement Award. The Polymer Division of the RACI has recognized Dave’s contributions to polymer science with the annual Solomon Lecture given by a prestigious polymer scientist.

Australian Journal of Chemistry 65(8) 945-969 https://doi.org/10.1071/CH12194
Submitted: 13 April 2012  Accepted: 17 May 2012   Published: 5 July 2012



50 articles found in Crossref database.

Metal Free Reversible-Deactivation Radical Polymerizations: Advances, Challenges, and Opportunities
Kreutzer Johannes, Yagci Yusuf
Polymers. 2017 10(1). p.35
Membrane Proteins in Aqueous Solutions (2018)
Popot Jean-Luc
Macromolecular Engineering (2022)
Moad Graeme
RAFT (Reversible addition-fragmentation chain transfer) crosslinking (co)polymerization of multi-olefinic monomers to form polymer networks
Moad Graeme
Polymer International. 2015 64(1). p.15
Cationic RAFT Polymerization Using ppm Concentrations of Organic Acid
Uchiyama Mineto, Satoh Kotaro, Kamigaito Masami
Angewandte Chemie International Edition. 2015 54(6). p.1924
Enzymatically Synthesized Vinyl Ether-Disulfide Monomer Enabling an Orthogonal Combination of Free Radical and Cationic Chemistry toward Sustainable Functional Networks
Brännström Sara, Johansson Mats, Malmström Eva
Biomacromolecules. 2019 20(3). p.1308
ChemInform Abstract: Origins of Nitroxide Mediated Polymerization (NMP) and Reversible Addition—Fragmentation Chain Transfer (RAFT)
Rizzardo Ezio, Solomon David H.
ChemInform. 2013 44(2).
Synthesis of bioactive polyaniline-b-polyacrylic acid copolymer nanofibrils as an effective antibacterial and anticancer agent in cancer therapy, especially for HT29 treatment
Bagheri Nazanin, Mansour Lakouraj Moslem, Nabavi Seyed Reza, Tashakkorian Hamed, Mohseni Mojtaba
RSC Advances. 2020 10(42). p.25290
USAXS analysis of concentration-dependent self-assembling of polymer-brush-modified nanoparticles in ionic liquid: [I] concentrated-brush regime
Nakanishi Yohei, Ishige Ryohei, Ogawa Hiroki, Sakakibara Keita, Ohno Kohji, Morinaga Takashi, Sato Takaya, Kanaya Toshiji, Tsujii Yoshinobu
The Journal of Chemical Physics. 2018 148(12).
Construction of Vinyl Polymer and Polyester or Polyamide Units in a Single Polymer Chain via Metal-catalyzed Simultaneous Chain- and Step-growth Radical Polymerization of Various Monomers
Mizutani Masato, Satoh Kotaro, Kamigaito Masami
Australian Journal of Chemistry. 2014 67(4). p.544
Development and Experimental Validation of a Dispersity Model for In Silico RAFT Polymerization
Wilding Clarissa. Y. P., Knox Stephen. T., Bourne Richard. A., Warren Nicholas. J.
Macromolecules. 2023 56(4). p.1581
Cationic RAFT Polymerization Using ppm Concentrations of Organic Acid
Uchiyama Mineto, Satoh Kotaro, Kamigaito Masami
Angewandte Chemie. 2015 127(6). p.1944
A detailed mechanistic study of bulk MADIX of styrene and its chain extension
Devlaminck Dries J. G., Van Steenberge Paul H. M., De Keer Lies, Reyniers Marie-Françoise, D'hooge Dagmar R.
Polymer Chemistry. 2017 8(45). p.6948
Radical Reactions (2023)
Determining the effect of side reactions on product distributions in RAFT polymerization by MALDI-TOF MS
Veloso Antonio, García Wendy, Agirre Amaia, Ballard Nicholas, Ruipérez Fernando, de la Cal José C., Asua José M.
Polymer Chemistry. 2015 6(30). p.5437
Determination of the Mode of Radical Termination from Pulsed Laser Polymerization Experiments in the Presence of Retardation and Chain Transfer to Agent
Nikitin Anatoly N., Hutchinson Robin A., Hesse Pascal
Macromolecular Chemistry and Physics. 2013 214(23). p.2670
Controlled growth of protein resistant PHEMA brushes via S-RAFT polymerization
Zamfir Mirela, Rodriguez-Emmenegger Cesar, Bauer Stella, Barner Leonie, Rosenhahn Axel, Barner-Kowollik Christopher
Journal of Materials Chemistry B. 2013 1(44). p.6027
“Smart” stimuli-responsive biomaterials revolutionizing the theranostic landscape of inflammatory arthritis
Nag Sagnik, Mohanto Sourav, Ahmed Mohammed Gulzar, Subramaniyan Vetriselvan
Materials Today Chemistry. 2024 39 p.102178
“One-pot direct synthesis of novel antibacterial diblock copolymers-based-vinyl acetate via RAFT polymerization”
Asif Iram, Gilani Syeda Rubina, Shahzadi Phool, Sabir Shaista
Journal of Polymer Research. 2021 28(4).
Star Polymers
Ren Jing M., McKenzie Thomas G., Fu Qiang, Wong Edgar H. H., Xu Jiangtao, An Zesheng, Shanmugam Sivaprakash, Davis Thomas P., Boyer Cyrille, Qiao Greg G.
Chemical Reviews. 2016 116(12). p.6743
SI-PET-RAFT in flow: improved control over polymer brush growth
Kuzmyn Andriy R., van Galen Martijn, van Lagen Barend, Zuilhof Han
Polymer Chemistry. 2023 14(29). p.3357
Rheological Properties of Multi-Block Associative Polyelectrolytes Obtained by Nitroxide-Mediated Solution Polymerization
Coronado Alejandro, Velazquez Areli I., Jiménez Enrique J.
MRS Proceedings. 2014 1613 p.143
A polyion complex micelle with heparin for growth factor delivery and uptake into cells
Zhao Yue, Lord Megan S., Stenzel Martina H.
Journal of Materials Chemistry B. 2013 1(11). p.1635
Bromoform-assisted aqueous free radical polymerisation: a simple, inexpensive route for the preparation of block copolymers
Hutchins-Crawford Helena J., Ninjiaranai Padarat, Derry Matthew J., Molloy Robert, Tighe Brian J., Topham Paul D.
Polymer Chemistry. 2021 12(30). p.4317
Disulfide-Functionalized Unimolecular Micelles as Selective Redox-Responsive Nanocarriers
Porsch Christian, Zhang Yuning, Montañez Maria I., Malho Jani-Markus, Kostiainen Mauri A., Nyström Andreas M., Malmström Eva
Biomacromolecules. 2015 16(9). p.2872
Ultrasensitive Impedimetric Immunosensor for the Detection of C-Reactive Protein in Blood at Surface-Initiated-Reversible Addition–Fragmentation Chain Transfer Generated Poly(2-hydroxyethyl methacrylate) Brushes
Kanyong Prosper, Catli Candan, Davis Jason J.
Analytical Chemistry. 2020 92(7). p.4707
Post‐polymerization modification by nitroxide radical coupling
Coiai Serena, Passaglia Elisa, Cicogna Francesca
Polymer International. 2019 68(1). p.27
Well-defined polyvinylpyridine-block-polystyrene diblock copolymers via RAFT aqueous-alcoholic dispersion polymerization: synthesis and isoporous thin film morphology
Nieswandt Katharina, Georgopanos Prokopios, Abetz Volker
Polymer Chemistry. 2021 12(15). p.2210
Why Are Organotin Hydride Reductions of Organic Halides So Frequently Retarded? Kinetic Studies, Analyses, and a Few Remedies
Ingold K. U., Bowry Vincent W.
The Journal of Organic Chemistry. 2015 80(3). p.1321
Biomedical applications of polymers derived by reversible addition – fragmentation chain-transfer (RAFT)
Fairbanks Benjamin D., Gunatillake Pathiraja A., Meagher Laurence
Advanced Drug Delivery Reviews. 2015 91 p.141
Polymeric Micelles: Principles, Perspectives and Practices (2023)
Arora Vimal, Bhandari Divya Dhawal, Puri Ritika, Khatri Naveen, Dureja Harish
Reversible-Deactivation Radical Polymerisation: chain polymerisation made simple
Bagheri Ali, Boniface Suzanne, Fellows Christopher M.
Chemistry Teacher International . 2021 3(2). p.19
Reference Module in Materials Science and Materials Engineering (2016)
Moad G., Rizzardo E., Thang S.H.
Synthesis of Poly(3-vinylpyridine)-Block-Polystyrene Diblock Copolymers via Surfactant-Free RAFT Emulsion Polymerization
Nieswandt Katharina, Georgopanos Prokopios, Abetz Clarissa, Filiz Volkan, Abetz Volker
Materials. 2019 12(19). p.3145
Poly(octadecyl methacrylate) via RAFT Technique and Its Rheological Study for Waxy Crude
Dutta Pranjal P., Mohan Bitupan, Saikia Prakash J.
Industrial & Engineering Chemistry Research. 2024 63(25). p.10879
Linear Block Copolymer Synthesis
Dau Huong, Jones Glen R., Tsogtgerel Enkhjargal, Nguyen Dung, Keyes Anthony, Liu Yu-Sheng, Rauf Hasaan, Ordonez Estela, Puchelle Valentin, Basbug Alhan Hatice, Zhao Chenying, Harth Eva
Chemical Reviews. 2022 122(18). p.14471
Green Synthetic Processes and Procedures (2019)
Montolio Silvia, Altava Belén, García-Verdugo Eduardo, Luis Santiago V.
TEMPO Driven Mild and Modular Route to Functionalized Microparticles
Hafeez Sumbul, Barner Leonie, Nebhani Leena
Macromolecular Rapid Communications. 2018 39(19).
pH-Sensitive C–ON Bond Homolysis of Alkoxyamines of Imidazoline Series: A Theoretical Study
Parkhomenko Dmitriy A., Edeleva Mariya V., Kiselev Vitaly G., Bagryanskaya Elena G.
The Journal of Physical Chemistry B. 2014 118(20). p.5542
Improving Recycled Poly(lactic Acid) Biopolymer Properties by Chain Extension Using Block Copolymers Synthesized by Nitroxide-Mediated Polymerization (NMP)
Benvenuta-Tapia Juan José, Champagne Pascale, Tenorio-López José Alfredo, Vivaldo-Lima Eduardo, Guerrero-Santos Ramiro
Polymers. 2021 13(16). p.2791
33rd Australasian Polymer Symposium
Perrier Sébastien
Australian Journal of Chemistry. 2012 65(8). p.943
Current trends in the development of HPMA-based block copolymeric nanoparticles for their application in drug delivery
Bobde Yamini, Biswas Swati, Ghosh Balaram
European Polymer Journal. 2020 139 p.110018
Polymer brushes: Synthesis, characterization, properties and applications
Murad Bhayo Adnan, Yang Yang, He Xiangming
Progress in Materials Science. 2022 130 p.101000
Modular Assembly of Poly(naphthalene diimide) and Ru(II) Dyes for an Efficient Light-Induced Charge Separation in Hierarchically Controlled Polymer Architectures
Schroot Robert, Schlotthauer Tina, Schubert Ulrich S., Jäger Michael
Macromolecules. 2016 49(6). p.2112
Size effects of self-assembled block copolymer spherical micelles and vesicles on cellular uptake in human colon carcinoma cells
Chang Teddy, Lord Megan S., Bergmann Björn, Macmillan Alex, Stenzel Martina H.
J. Mater. Chem. B. 2014 2(19). p.2883
A guide to the synthesis of block copolymers using reversible-addition fragmentation chain transfer (RAFT) polymerization
Keddie Daniel J.
Chem. Soc. Rev.. 2014 43(2). p.496
Hyperbranched polydendrons: a new controlled macromolecular architecture with self-assembly in water and organic solvents
Hatton Fiona L., Chambon Pierre, McDonald Tom O., Owen Andrew, Rannard Steven P.
Chem. Sci.. 2014 5(5). p.1844
Controlled Radical Polymerization: Mechanisms (2015)
Moad Graeme
Functional group tolerance of AOTEMPO-mediated peroxide cure chemistry
Molloy Brian M., Johnson Kelli-anne, Ross Rachel J., Parent J. Scott
Polymer. 2016 99 p.598
Nitroxide radical polymers – a versatile material class for high-tech applications
Hansen Kai-Anders, Blinco James P.
Polymer Chemistry. 2018 9(13). p.1479

Committee on Publication Ethics

Abstract Full Text PDF (3.6 MB) Export Citation Get Permission

Share

Share on Facebook Share on Twitter Share on LinkedIn Share via Email