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Assembly of the 1-Azaspiro[5.5]undecane Framework Associated with Perhydrohistrionicotoxin via Electrocyclic Ring-Opening of a Ring-Fused gem-Dichlorocyclopropane and Trapping of the Resulting π-Allyl Cation by a Tethered, Nitrogen-Centered Nucleophile

Martin G. Banwell A C , Florian Vogt A and Angela W. Wu B
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A Research School of Chemistry, Australian National University, Canberra ACT 0200, Australia.

B School of Chemistry, University of Melbourne, Parkville VIC 3052, Australia.

C Corresponding author. Email: mgb@rsc.anu.edu.au

Australian Journal of Chemistry 59(7) 415-425 https://doi.org/10.1071/CH06218
Submitted: 21 June 2006  Accepted: 24 July 2006   Published: 22 August 2006



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