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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Selective Bromochlorination of endo-1,4-Dibromotricyclo[5.2.1.02,6]deca-3,8-diene-5,10-dione 10-Ethylene Acetal at the Conjugated Carbon-Carbon Double Bond

RW Gable, KJ Parker and J Tsanaktsidis

Australian Journal of Chemistry 47(5) 963 - 968
Published: 1994

Abstract

Exposure of (1) to bromine in thionyl chloride/ dimethylformamide produced (5), the result of regio- and stereo-selective addition of bromine chloride across the carbonyl-conjugated double bond. The structure of (5) was determined by X-ray crystallography, and its mode of formation is discussed in terms of the carbonyl attack mechanism.

https://doi.org/10.1071/CH9940963

© CSIRO 1994

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