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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The Stereochemistry of Organometallic Compounds. XXXIX. Hydroformylation of Alkenes Containing Sulfur and Oxygen Substituents: a Potential Route to 1,4-Dialdehydes

EM Campi, WR Jackson, P Perlmutter and EE Tasdelen

Australian Journal of Chemistry 46(7) 995 - 1007
Published: 1993

Abstract

Rhodium-catalysed hydroformylation of a series of unsaturated thioethers, dithians , dioxans and dioxolans has been shown to give aldehydes in very good yield. The regioselectivity in some cases appears to be influenced by coordination between the rhodium catalyst and the sulfur substituent especially when dodecacarbonyltetrarhodium is used as the catalyst precursor. At tempts to convert dithian and dioxan aldehydes into 1,4-dialdehydes were unsuccessful.

https://doi.org/10.1071/CH9930995

© CSIRO 1993

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