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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The Intermediacy of Free Aryl Radicals in the Reaction of o-Alkenyloxybenzenediazonium Salts With Ferrocene

ALJ Beckwith, RA Jackson and RW Longmore

Australian Journal of Chemistry 45(5) 857 - 863
Published: 1992

Abstract

The formation of 3-ferrocenylmethyl-2,3-dihydrobenzofuran (5a) and similar products bearing cyclized substituents, when ferrocene or mixtures of ferrocene and ferrocenium ion are treated witho - allyloxybenzene - or o-but-3-enyloxybenzene-dimonium salts, provides unequivocal evidence for the intermediacy of free aryl radicals in the reaction of ferrocene with arenediazonium salts. The results are consistent with a mechanism involving electron transfer and dediazoniation followed by homolytic attack on ferroce nium ion.

https://doi.org/10.1071/CH9920857

© CSIRO 1992

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