The Stereochemistry of Organometallic Compounds. XXXVII. Regio and Stereo-control in the Rhodium-Catalyzed Hydroformylation of Some Alkenylphosphines

Abstract

Good to excellent regiocontrol can be obtained for the internal product of rhodium- catalysed hydroformylation of a range of alkenylphosphines. Excellent stereo- as well as regio-control can also be obtained for reactions of some cyclic alkenylphosphines.