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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The Two-Step Hydrolysis of Dimethoxo(tetraphenylporphyrinato)tin(IV)

HJ Lin, HJ Lin, JH Chen, JH Chen, LP Hwang and LP Hwang

Australian Journal of Chemistry 44(5) 747 - 751
Published: 1991

Abstract

The hydrolysis of dimethoxo ( tetraphenylporphyrinato )tin(IV), Sn ( tpp )( OMe )2 was studied by n.m.r. spectroscopy. The use of specially dehydrated CDCl3 allowed the hydrolysis intermediate hydroxomethoxo (tetraphenylporphyrinato )tin(IV) Sn ( tpp )( OMe )(OH), to be identified. The results show that the second step, of the two-step hydrolysis, is rate limiting.

https://doi.org/10.1071/CH9910747

© CSIRO 1991

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