A Hydroformylation Route to Diazabicycloalkanes and Oxazabicycloalkanes Containing Medium and Large Rings
David J. Bergmann, Eva M. Campi,
W. Roy Jackson and Antonio F. Patti
Australian Journal of Chemistry
52(12) 1131 - 1138
Published: 1999
Abstract
Diazabicycloalkanes and oxazabicycloalkanes containing medium and large rings can be prepared by rhodium-catalysed reactions of N-alkenylpropane-1,3-diamines and 2-(alkenylamino)ethanols with H2/CO in excellent yields without the need for high dilution. Selective ring opening of these compounds can lead to large heterocycles.https://doi.org/10.1071/CH99097
© CSIRO 1999
