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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Stability Constants of Silver(I) Complexes of Bis(2-chloroethyl) Sulfide (Sulfur Mustard) and Some Related Thioethers in Polar Organic Solvents

RI Tilley

Australian Journal of Chemistry 43(9) 1573 - 1576
Published: 1990

Abstract

Stability constants of complexes formed between silver(I) and diethyl sulfide, 2-chloroethyl ethyl sulfide and bis (2-chloroethyl) sulfide (sulfur mustard) in acetone, methanol, dimethylformamide and dimethyl sulfoxide have been determined. The reduced stability of silver(I) complexes with ligands containing a 2-chloroethyl group has been explained in terms of the sulfonium ion character of the ligands.

https://doi.org/10.1071/CH9901573

© CSIRO 1990

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