Free Standard AU & NZ Shipping For All Book Orders Over $80!
Register      Login
Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The Interaction of Triosmium Clusters with Pyridinethiols: the Crystal and Molecular Structures of [{Os3(µ-H)(CO)10}2(µ-S2C4H2N2)]and [Os3(µ-H)(CO)10(µ-SC5H4N)]

Eric W. Ainscough, Andrew M. Brodie, Richard K. Coll and Joyce M. Waters

Australian Journal of Chemistry 52(8) 801 - 806
Published: 1999

Abstract

Pyrimidine-2,4-dithiol [HL 1 = (HS)2C4H2N2] and pyridine-2-thiol [HL 2 = (HS)C5H4N] form the osmium clusters [{Os3(µ-H)(CO)10}2(µ-S2C4H2N2)] and [Os3(µ-H)(CO)10(µ-SC5H4N)], each of which contain chelating µ,η1-thiolate ligands and hydride bridges across common edges of the osmium triangles. In the former complex two osmium triangles are linked together by the pyrimidinedithiolato ligand.

https://doi.org/10.1071/CH99002

© CSIRO 1999

Committee on Publication Ethics


Export Citation Get Permission

View Dimensions