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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The Stereochemistry of Organometallic Compounds. XXXIV. Regioselection in the Hydroformylation of Silylalkenes

MM Doyle, WR Jackson and P Perlmutter

Australian Journal of Chemistry 42(11) 1907 - 1918
Published: 1989

Abstract

The regiochemistry of hydroformylation of alkenes can be controlled by the use of bulky silyl groups attached to the alkene. Use of the t-butyldiphenylsilyl group leads to almost total regiocontrol and the method has been applied to the synthesis of aldols.

https://doi.org/10.1071/CH9891907

© CSIRO 1989

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