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Australian Journal of Chemistry Australian Journal of Chemistry Society
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RESEARCH ARTICLE

Coordination of the Hexacyanoferrate(III) Anion to a Polyammonium Macrocycle. Crysta -Structure of [H4L]1.5[Fe(CN)6]2 (L=6,13-Dimethyl-1,4,8,11-tetraaza-cyclotetradecane-6,13-diamine)

PV Bernhardt, GA Lawrance, BW Skelton and AH White

Australian Journal of Chemistry 42(7) 1035 - 1043
Published: 1989

Abstract

Crystals of [H4L]1.5[Fe(CN)6]2.3H2O.¾HCN form readily from an aqueous solution of L=6HCI (L = 6,13-dimethyl-1,4,8,11- tetraazacyclotetradecane-6,13-diamine) and Na3 [Fe(CN)6]. The compound is monoclinic, space group P21/c, a 7.982(6), b 20.785(3), c 26.81(1) Å , β 101.37(5), Z = 4. Protonation is complete at the terminal primary nitrogens, but in the ring one trans pair is protonated and the other not, with short trans H…H distances. Hydrogen-bonding interactions are a feature of the structure, but are concentrated more strongly at the terminal NH3+ groups. Interactions of [Fe(CN)6]3- nitrogens with both terminal amine protons and macrocycle ring amine protons are observed, and this structure represents a further example of a 'super complex' involving a complex anion and a protonated polyaza macrocycle.

https://doi.org/10.1071/CH9891035

© CSIRO 1989

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