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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The Influence of Pressure on the Infrared-Spectra of Hydrogen-Bonded Solids. VII. Deuterated Ammonium Salts

SD Hamann

Australian Journal of Chemistry 41(12) 1935 - 1941
Published: 1988

Abstract

The infrared stretching and bending frequencies of isotopically dilute +NHD3 ions in predominantly +ND4 salts have been measured at pressures up to 5 GPa at 25°C. For most of the 28 salts studied, the stretching bands move to higher frequencies with increasing pressure, these results suggesting the absence of any significant hydrogen bonding between the ammonium ions and the anions in the crystals.

https://doi.org/10.1071/CH9881935

© CSIRO 1988

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