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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Cluster Chemistry. XLI. P-C Bond Cleavage Reactions of Ru3(µ-dppm)(CO)10. Synthesis and Crystal Structure of Ru33-PPhCH2PPh(C6H4)](CO)9

MI Bruce, PA Humphrey, BW Skelton, AH White and ML Williams

Australian Journal of Chemistry 38(9) 1301 - 1306
Published: 1985

Abstract

Thermolysis of Ru3(μ- dppm )(CO)10 (1) results in cyclometallation and dephenylation to give the title complex. This complex is also formed, together with Ru3(μ-H)(μ3-PPhCH2PPh2(CO)9, from reaction between (1) with HC5(CO2Me)5.

https://doi.org/10.1071/CH9851301

© CSIRO 1985

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