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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The stereochemistry of organometallic compounds. XXIII. Synthesis of a chiral diphosphinite (diphin) and evaluation of its use as a ligand for asymmetric catalysis

WR Jackson and CG Lovel

Australian Journal of Chemistry 35(10) 2069 - 2075
Published: 1982

Abstract

(+)-(3S,4S)-Tetrahydrofuran-3,4-diyl bis(diphenylphosphinite) [(+)-diphin] has been synthesized and its efficiency as a ligand in asymmetric hydrogenation, hydrocyanation and hydroformylation compared with closely related diphosphine, diphosphinite and diphosphite ligands.

https://doi.org/10.1071/CH9822069

© CSIRO 1982

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