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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The anodic oxidation of silver in sulfide solutions

GD Campbell, FJ Lincoln, GP Power and IM Ritchie

Australian Journal of Chemistry 35(6) 1079 - 1085
Published: 1982

Abstract

This work extends a previous study on the electrochemistry of silver electrodes in aqueous sulfide solutions.

It has been found that the voltammograms for the silver-sulfide system have additional features to those reported earlier. The nature and interpretation of the additional features is described. Peaks due to silver oxides, and chemically formed silver sulfide, are identified and discussed. Further evidence for the presence of α- and β-Ag2S in the layer deposited during anodic oxidation of the silver was obtained from chronopotentiometric and diffraction studies.

https://doi.org/10.1071/CH9821079

© CSIRO 1982

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