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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Carbonyl halides of the Group VI transition metals. XXVII. Carbon-13 N.M.R. studies on molybdenum compounds

R Colton and J Kevekordes

Australian Journal of Chemistry 35(5) 895 - 901
Published: 1982

Abstract

Carbon-13 nuclear magnetic resonance studies have been carried out on a number of molybdenum(II) carbonyl halide species. It has been found that for these seven-coordinate capped octahedral complexes there is a very large shift to high frequency for a carbonyl group in the capping position. Thus carbon-13 n.m.r. provides a useful tool to distinguish between possible isomers. Trends in stability and isomer formation previously suspected from circumstantial evidence can now be rationalized.

https://doi.org/10.1071/CH9820895

© CSIRO 1982

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