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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The structure and synthesis of cytokinin metabolites. III. 13C N.M.R. of cytokinin glycosides

CC Duke and JK Macleod

Australian Journal of Chemistry 31(10) 2219 - 2223
Published: 1978

Abstract

The 13C N.M.R. spectra of the cytokinins (1)-(3) and cytokinin glycosides (4)-(11) are reported and complete assignments made by correlation with related compounds and with the aid of deuterium labelling. The results show that previously derived 13C N.M.R. correlations on simpler purine derivatives can be extended to the cytokinin glucosides for the determination of the substitution positions on the adenine ring. As well, the structure of the substituents and the stereochemistry of the N-glu-cosyl linkages can be confirmed from 13C chemical shift values.

https://doi.org/10.1071/CH9782219

© CSIRO 1978

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