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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

An N.M.R. investigation of the metal-ligand bonding in some transition metal complexes of Bicyclo[3,3,1]nona-2,6-diene

R Bishop

Australian Journal of Chemistry 31(7) 1485 - 1492
Published: 1978

Abstract

The structure of the bicyclo[3,3,1]nona-2,6-diene complexes with formulae (diene)PdCl2, (diene)PtCl2, and [(diene)RhCl]2 has been shown, by use of 1H and 13C N.M.R. spectroscopy and deuterium labelling, to involve two equivalent metal-olefin bonds preferentially bonded to carbon atoms 2 and 6. Two crystalline forms (α, β) of the palladium complex were obtained. These were completely inter-convertible in either direction from solution, with the a-form being converted into the P-form (with concurrent halogen exchange) under i.r. KBr disc conditions.

https://doi.org/10.1071/CH9781485

© CSIRO 1978

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