Vinylindenes and some heteroanalogues in the Diels-Alder reaction. IV. Reactions of ethenetetracarbonitrile with some 3-vinylindoles
R Bergamasco, QN Porter and C Yap
Australian Journal of Chemistry
30(7) 1531 - 1544
Published: 1977
Abstract
3-Vinylindoles are conveniently prepared from methylenetriphenylphosphorane and indole-3-carbaldehydes. Those studied give normal Diels-Alder adducts with ethenetetracarbonitrile, except in the case of the 2-methyl derivative, where steric hindrance results in formation of a cyclobuty-indole. The adducts are relatively unstable, and decompose rapidly to indolylbutadienetricarbonitriles.https://doi.org/10.1071/CH9771531
© CSIRO 1977