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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Correlation of 13C N.M.R. shifts with chemical reactivity in phenethyl systems

LF Blackwell, PD Buckley and KW Jolley

Australian Journal of Chemistry 29(11) 2423 - 2429
Published: 1976

Abstract

Correlations between 13C substituent-induced chemical shifts (scs) for carbon atoms in substituted phenethyl bromides, dimethylphenethylsulphonium bromides and ethylbenzenes have been examined. C1 13C scs were found to correlate with Hammett D values as expected from previous results with 1H scs. The β-carbons showed no correlation while the α-carbons showed an inverse linear relationship with the electron-withdrawing power of the substituents.

https://doi.org/10.1071/CH9762423

© CSIRO 1976

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