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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The zinc gluconate system

PW Roller and WF Pickering

Australian Journal of Chemistry 29(11) 2395 - 2403
Published: 1976

Abstract

A study of the zinc gluconate system has shown that, in solutions of pH <6, one, two or four gluconate ions can be coordinated to the metal ion. Above pH 6 a gel is formed [formula Zn2(glH4)(OH)3,xH2O, pKsp'28]; this slowly transforms into Zn(OH)2 at pH >7. Formation of soluble zincates occurs at pH >10. Two solid compounds [Zn(glH4)2 3H2O and Zn2(glH3)(OH)2] have been isolated and subjected to spectral and thermal examination.

https://doi.org/10.1071/CH9762395

© CSIRO 1976

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