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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Volatility studies of metal chelates. II. Gas chromatographic properties of vanadium β-diketonates

S Dilli and E Patsalides

Australian Journal of Chemistry 29(11) 2381 - 2388
Published: 1976

Abstract

The gas chromatographic elution behaviour is reported for a total of 16 vanadium(111) and oxovanadium(1V) fluorinated β-diketonates on a column consisting of a lightly loaded, non-polar stationary phase and diatomite support. The superiority of the vanadium(111) chelates is shown to include electron-capture detection. Detection limits of 14 chelates are given for the flame ionization detector. Separation of the two oxidation states of a metal by gas-liquid chromatography is demonstrated for the first time.

https://doi.org/10.1071/CH9762381

© CSIRO 1976

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