Register      Login
Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The chemistry of pyrrolic compounds. XXIX. Synthesis of some derivatives of deuteroporphyrin-IX

PS Clezy and V Diakiw

Australian Journal of Chemistry 28(7) 1589 - 1604
Published: 1975

Abstract

The synthesis of the 2- and 4-acetyl-, and the 2- and 4- methoxycarbonyl-deuteroporphyrin-IX dimethyl esters has been achieved by the oxidative cyclization of bilene-b intermediates. Interconversion of the acetyl- and methoxycarbonyl-deuteroporphyrins has been carried out via the hydroxyethyl, vinyl and formyl derivatives. In this way the structural assignments of the two series of isomers have been rigorously defined and this has necessitated revision of earlier formulations.

https://doi.org/10.1071/CH9751589

© CSIRO 1975

Committee on Publication Ethics


Export Citation Get Permission

View Dimensions