Mixed cations of sulphur in disulphuric acid
A Bali and KC Malhotra
Australian Journal of Chemistry
28(5) 983 - 990
Published: 1975
Abstract
Sulphur monochloride and dichloride form S82+ and SCl3+ ions when dissolved in disulphuric acid. In the presence of halogens, sulphur dichloride forms SX3+ ions while sulphur monochloride forms S2Cl3+ and S2Br3+ which disproportionate to form SX3+ and sulphur. SX3+ ions are formed when sulphur is dissolved in disulphuric acid containing chlorine or bromine or when halogens are added to the colourless solution of S42+ ions in disulphuric acid.https://doi.org/10.1071/CH9750983
© CSIRO 1975