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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Mixed cations of sulphur in disulphuric acid

A Bali and KC Malhotra

Australian Journal of Chemistry 28(5) 983 - 990
Published: 1975

Abstract

Sulphur monochloride and dichloride form S82+ and SCl3+ ions when dissolved in disulphuric acid. In the presence of halogens, sulphur dichloride forms SX3+ ions while sulphur monochloride forms S2Cl3+ and S2Br3+ which disproportionate to form SX3+ and sulphur. SX3+ ions are formed when sulphur is dissolved in disulphuric acid containing chlorine or bromine or when halogens are added to the colourless solution of S42+ ions in disulphuric acid.

https://doi.org/10.1071/CH9750983

© CSIRO 1975

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