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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Unusual products from the cyanide displacement reaction of methyl 5-Chloromethylfuran-2-carboxylate

TM Cresp and MV Sargent

Australian Journal of Chemistry 27(4) 905 - 908
Published: 1974

Abstract

Treatment of the title chloro compound (9) with sodium cyanide in N,N-dimethylformamide or dimethyl sulphoxide yielded methyl 2-cyan;-2,5-dihydro-5-(5'-methoxycarbonylfurfurylmethylene)-furan-2-carboxylate (12) and methyl 2-cyano-2,5-dihydro-5-[bis(5'-methoxycarbonylfurfuryl)methylenelfuran-2-carboxylate (13) as well as methyl 5-cyanomethylfuran-2-carboxylate (8).

https://doi.org/10.1071/CH9740905

© CSIRO 1974

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