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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Carbon and hydrogen scrambling in the ions C(9+n)H(9+2n)+. Rearrangements of cyclooctatetraene derivatives

JH Bowie, GE Gream and M Mular

Australian Journal of Chemistry 25(5) 1107 - 1115
Published: 1972

Abstract

Carbon and hydrogen scrambling occurs either prior to, or during, the decompositions of the ions C9H9+, CllH13+, and C12H15+ in the first field-free region of the mass spectrometer. The ions may be produced from various substrates, and the decompositions of CllH13+ may be interpreted in terms of a decomposing ion in which some, but not all, of the C-H bonds have broken and reformed. The ions C9H9+ and C10H11+ may be produced by complex hydrogen rearrangement in the side-chain of particular bromo-and hydroxy-alkylcyclooctatetraene derivatives.

https://doi.org/10.1071/CH9721107

© CSIRO 1972

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