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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The cobalt(II)-triethylenetetramine system in acetonitrile solution. A nitrogen-14 magnetic resonance and spectrophotometric study

SF Lincoln and RJ West

Australian Journal of Chemistry 25(3) 469 - 476
Published: 1972

Abstract

A nitrogen-14 magnetic resonance and spectrophotometric study of the cobalt(11)-triethylenetetramine (trien) system in acetonitrile solvent indicates the presence of the predominant species Co(CH3CN)62+ Co(trien)(CH3CN)n2+ where n = 1 or 2, Co2(trien)34+, and Co(trien)22+ in solution. The lability of CH3CN in the first coordination sphere is shown to be > 103 times that of CH3CN in the first coordination sphere of CO(CH3CX)62+ at 258 K.

https://doi.org/10.1071/CH9720469

© CSIRO 1972

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