Free Standard AU & NZ Shipping For All Book Orders Over $80!
Register      Login
Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Steroid hormones. XXI. Some testosterone derivatives substituted at C19

AJ Birch and B McKague

Australian Journal of Chemistry 23(2) 341 - 346
Published: 1970

Abstract

Addition of but-1-en-3-one to (1) produced the adducts (28) and (2b) which undergo ring fission with acid to give (3). Methylmagnesium iodide on (2a) and (2b) gives the alcohol mixture (4) which is converted by acid into (5). A similar series of reactions with derivatives of l,2-dihydrooestrone methyl ether gives the steroid (10) and the 17β-OH analogue, and (11) containing an angular isoprene unit.

https://doi.org/10.1071/CH9700341

© CSIRO 1970

Committee on Publication Ethics


Export Citation Get Permission

View Dimensions