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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The stereospecific solvation of non-polar organic solutes in liquid benzene

FFvre RJW Le, DSN Murthy and PJ Stiles

Australian Journal of Chemistry 22(7) 1421 - 1426
Published: 1969

Abstract

The molar Cotton-Mouton constants of several non-polar and axially symmetric solutes have been measured in both benzene and carbon tetrachloride. Differences between the Cotton-Mouton constants of the same solute in these two solvents are largely attributable to angular correlations between the solute and the benzene molecules. Hexafluorobenzene and 1,3,5-trinitrobenzene reveal pronounced tendencies towards parallel alignment of solute and neighbouring benzene molecules.

https://doi.org/10.1071/CH9691421

© CSIRO 1969

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