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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The potential dependence and upper limit of electrochemical charge transfer rates

DB Matthews

Australian Journal of Chemistry 22(7) 1349 - 1353
Published: 1969

Abstract

A theory is developed to predict the potential dependence at high rates, and the upper limit, of electrochemical charge transfer reactions. The theory utilizes a constant symmetry factor and shows how the properties of the overlapping electron distribution functions produce a non-linear dependence of log(rate) on electrode potential, and hence a dependence of the effective symmetry factor on electrode potential.

https://doi.org/10.1071/CH9691349

© CSIRO 1969

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