The potential dependence and upper limit of electrochemical charge transfer rates
DB Matthews
Australian Journal of Chemistry
22(7) 1349 - 1353
Published: 1969
Abstract
A theory is developed to predict the potential dependence at high rates, and the upper limit, of electrochemical charge transfer reactions. The theory utilizes a constant symmetry factor and shows how the properties of the overlapping electron distribution functions produce a non-linear dependence of log(rate) on electrode potential, and hence a dependence of the effective symmetry factor on electrode potential.https://doi.org/10.1071/CH9691349
© CSIRO 1969