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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Pyrrole studies. V. Applications of the Wittig reaction to the synthesis of substituted pyrroles

RA Jones and JA Lindner

Australian Journal of Chemistry 18(6) 875 - 885
Published: 1965

Abstract

    trans-1-(2-Pyrrolyl)but-1-en-3-one, trans-1-(1-methyl-2-pyrrolyl)but-1-en-3-one, ethyl trans-2-(2-pyrrolyl)acrylate, ethyl trans-2-(1-methyl-2-pyrrolyl)acrylate, 2-vinylpyrrole, 1-methyl-2-vinylpyrrole, and the cis and trans isomers of 2-styrylpyrrole, 1-methyl-2-styrylpyrrole, and 1-phenyl-2-(2-pyrrolyl)prop-1-ene have been prepared using the Wittig reaction. The electronic and infrared spectra of these compounds are recorded. The modified Wittig reaction, using diethyl phosphonates, is only satisfactory with N-substituted carbonylpyrroles.

https://doi.org/10.1071/CH9650875

© CSIRO 1965

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