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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

A Study of the Thorpe-Ingold Effect: The Reaction of Potassium Hydroxide with a Lactone of Ethyl α-Bromo-α'-hydroxy-1,1-cyclohexane Diacetate

HO Larson and GSK Sung

Australian Journal of Chemistry 15(2) 261 - 264
Published: 1962

Abstract

Treatment of a lactone of ethyl α-bromo-α?-hydroxy-1,1-cyclohexane diacetate with aqueous potassium hydroxide formed αα'-dihydroxyl-1,1-cyclohexanediacetic acid. The cyclohexanespirocyclopropanol-2,3-dicarboxylic acid (I), an important member of a series of compounds illustrating ring-chain tautomerism, was not observed.

https://doi.org/10.1071/CH9620261

© CSIRO 1962

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