Some studies in inorganic complexes. IV. Titanium(III) and Titanium(IV)

Abstract

The titanium complexes TiCl₃.D.H₂O, TiBr₃.D.H₂O, TiCl₄.D, and TiBr₄.D, In which D is o-phenylenebisdimethylarsine. have been prepared and studied. By means of conductivity and molecular weight measurements, it has been shown that they are 6-covalent non-electrolytes. The thiocyanato complexes [NH₄][Ti(SCN)₄(H₂O)₂,], [NH₄][Ti(SCN)₄], and [NH₄][Ti(SCN)₄OH.H₂O] were also prepared and their structures verified by conductivity measurements.