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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Hydrogen Bonding in organic compounds. 1. o-Nitroanilines

LK Dyall and AN Hambly

Australian Journal of Chemistry 11(4) 513 - 528
Published: 1958

Abstract

The infra-red spectra of o-nitroanilines do not indicate any intramolecular hydrogen bonding unless there are nitro groups in both positions 2 and 6 to the amino group. An examination of the literature shows that there is no unambiguous evidence from other sources of such bonding in simple o-nitroanilines. An explanation is given of the variation of the stretching frequencies of the nitro group in sterically hindered compounds and in those with electron-donating ortho- and para-substituents.

https://doi.org/10.1071/CH9580513

© CSIRO 1958

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