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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The reaction of Sodium Acetylide with Benzil and related compounds

J Cymerman-Craig, M Moyle, P Rowe-Smith and PC Wailes

Australian Journal of Chemistry 9(3) 391 - 396
Published: 1956

Abstract

Attempted condensation of benzil and benzoin with sodium acetylide in liquid ammonia caused fission of the central carbon-carbon bond of these substances, giving 3-phenylprop-1-yn-3-ol. Condensation of α-bromodeoxyanisoin with the same reagent gave several non-acetylenic products which have been identified.

https://doi.org/10.1071/CH9560391

© CSIRO 1956

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