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RESEARCH ARTICLE
Contents Vol 77(1)

Lanthanide coordination polymers based on an aromatic dicarboxylic acid and 1,10-phenanthroline ligands: synthesis, structure and luminescence properties

Shu-Ju Wang A , Yang Liu A , Zhi-Qing Zhang A , Qian Li A , Gang Xiong A , Li-Xin You https://orcid.org/0000-0003-1017-3901 A * and Yaguang Sun https://orcid.org/0000-0001-5850-0938 A B *
+ Author Affiliations
- Author Affiliations

A Key Laboratory of Inorganic Molecule-based Chemistry of Liaoning Province, Shenyang University of Chemical Technology, Shenyang, 110142, PR China.

B Key Laboratory on Resources Chemicals and Material of Ministry of Education, Shenyang University of Chemical Technology, Shenyang, 110142, PR China.

* Correspondence to: youlx@syuct.edu.cn, sunyaguang@syuct.edu.cn

Handling Editor: Stuart Batten

Australian Journal of Chemistry 77, CH23149 https://doi.org/10.1071/CH23149
Submitted: 17 August 2023  Accepted: 22 November 2023  Published online: 12 December 2023

© 2024 The Author(s) (or their employer(s)). Published by CSIRO Publishing.

Abstract

A novel series of lanthanide coordination polymers (Ln-CPs) have been obtained based on mixed ligands, 2-[(4-carboxyphenyl)methoxy]benzoic acid (H2cob) and 1,10-phenanthroline (phen), namely {Ln[(Hcob)(cob)(phen)]n, Ln = La (1), Pr (2), Sm (3), Eu (4)}. Complexes 1–4 were characterized by single crystal X-ray diffraction, elemental analysis, powder X-ray diffraction, infrared spectroscopy and thermogravimetric analysis. Single crystal X-ray diffraction revealed that complexes 1–4 show two-dimensional layer structures. The luminescence properties of complexes 3 and 4 were thoroughly investigated.

Keywords: 1,10-phenanthroline, 2-[(4-carboxyphenyl)methoxy]benzoic acid, coordination polymer, crystal structure, lanthanide, luminescence, luminescence decay, mixed ligands.

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