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RESEARCH ARTICLE
Contents Vol 74(2)

Chiral BINAPO Induced Circularly Polarized Luminescence in a Triple-Stranded Eu2L3(BINAPO)2 Helicate

Shuang Bi https://orcid.org/0000-0002-6862-6910 A , Yanyan Zhou A , Yuan Yao A , Zhenyu Cheng A , Ting Gao https://orcid.org/0000-0002-6981-1886 A B , Pengfei Yan A and Hongfeng Li A B
+ Author Affiliations
- Author Affiliations

A Key Laboratory of Functional Inorganic Material Chemistry (Ministry of Education), School of Chemistry and Materials Science, Heilongjiang University, No. 74, Xuefu Road, Nangang District, Harbin 150080, China.

B Corresponding authors. Email: gaotingmail@sina.cn; lihongfeng@hlju.edu.cn

Australian Journal of Chemistry 74(2) 145-150 https://doi.org/10.1071/CH20074
Submitted: 5 March 2020  Accepted: 9 June 2020   Published: 9 July 2020

Abstract

Chiral lanthanide helicates with circularly polarized luminescence (CPL) properties have found potential application in bioanalyses and chirality sensing. However, the preparation of the enantiopure helicates through a coordination-directed self-assembly strategy is challenging due to the greatly labile coordination geometries of lanthanide ions. Herein, a pair of enantiopure triple-stranded EuIII helicates [(Eu2L3)(R/S-BINAPO)2] are assembled by three achiral C2-symmeric bis-β-diketones (4,4′-bis(4,4,4-trifluoro-1,3-dioxobutyl)(phenoxyl)-1,1′-biphenyl, L) helically twisting around two EuIII ions, and two chiral R/S-bis(diphenylphosphoryl)-1,1′-binaphthyl (R/S-BINAPO) as ancillary ligands. Electrospray ionization–mass spectrometry, NMR, and circular dichroism (CD) spectra confirm the formation of a pair of enantiopure chiral topological helicates (Eu2L3)(R-BINAPO)2 and (Eu2L3)(S-BINAPO)2. As expected, the helicates present strong CPL with the |glum| up to 0.09, and the higher luminescent quantum yields (QYs) of up to 51 %.


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