Mapping Out the Diversity of Lanthanide(iii) Coordination Complexes Involving p-Sulfonatocalix[4,6]arenes
Irene Ling
A F , Mohamed Makha B , Alexandre N. Sobolev C , Yatimah Alias D and Colin L. Raston E F
A School of Science, Monash University Malaysia, Jalan Lagoon Selatan, 47500 Bandar Sunway, Selangor, Malaysia.
B Suzhou Research Institute of LICP, Center for Excellence in Molecular Synthesis, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, China.
C School of Molecular Sciences, M310, The University of Western Australia, 35 Stirling Highway, Perth, WA 6009, Australia.
D Chemistry Department, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia.
E Flinders Institute for Nanoscale Science and Technology, College of Science and Engineering, Flinders University, Adelaide, SA 5042, Australia.
F Corresponding authors. Email: ireneling@monash.edu; colin.raston@flinders.edu.au
Australian Journal of Chemistry 73(6) 570-578 https://doi.org/10.1071/CH19640
Submitted: 11 December 2019 Accepted: 4 February 2020 Published: 19 March 2020
Abstract
Structurally authenticated complexes of the cone-shaped p-sulfonatocalix[4]arene and conformationally flexible p-sulfonatocalix[6]arene devoid of co-ligands/ancillary molecules are limited. Early and late members of the lanthanide series as their trivalent ions, La3+, Er3+, and Yb3+, form complexes from aqueous media under these conditions. For La3+ and Er3+, distinct hydrophobic and hydrophilic bilayers are formed with p-sulfonatocalix[4]arene, whereas for Yb3+, two complexes form that deviate from the well-known bilayer arrangement of calixarenes. Replacing the calixarene with p-sulfonatocalix[6]arene results in a hydrogen-bonded network with alternating hydrophobic–hydrophilic layers associated with primary coordination of Yb3+, with the larger macrocyclic calixarene in a partial cone conformation.
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