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RESEARCH ARTICLE
Contents Vol 72(10)

Three Manganese Complexes of Anionic N4-Donor Schiff-Base Macrocycles: Monomeric MnII and MnIII, and dimeric MnIV*

Rajni K. Wilson A , Sébastien Dhers A , Stephen Sproules B , Eric J. L. McInnes C and Sally Brooker https://orcid.org/0000-0002-5878-8238 A D
+ Author Affiliations
- Author Affiliations

A Department of Chemistry and MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, PO Box 56, Dunedin 9054, New Zealand.

B WestCHEM, School of Chemistry, University of Glasgow, Glasgow G12 8QQ, UK.

C School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester M13 9PL, UK.

D Corresponding author. Email: sbrooker@chemistry.otago.ac.nz

Australian Journal of Chemistry 72(10) 805-810 https://doi.org/10.1071/CH19209
Submitted: 10 May 2019  Accepted: 25 June 2019   Published: 26 July 2019

Abstract

Three manganese macrocyclic complexes of two anionic N4-donor [1 + 1] Schiff-base macrocycles that differ in ring size (14 versus 16 membered), HLEt and HLPr (obtained from condensation of diphenylamine-2,2′-dicarboxaldehyde and either diethylenetriamine or dipropylenetriamine), are reported. Specifically, a pair of monomeric complexes MnIILEt(NCS)(H2O) and [MnIIILPr(NCS)2]·0.5H2O, plus a dimeric complex [MnIV2LEt2(O)2](ClO4)2·3DMF have been synthesised and characterised. Single crystal structure determinations on [MnIIILPr(NCS)2]·0.5H2O and [MnIV2LEt2(O)2](ClO4)2·3DMF revealed octahedral manganese centres in both cases: N6-coordinated Jahn–Teller distorted MnIII in the former and a pair of N4O2-coordinated MnIV in the latter. UV-Vis, IR, and electron paramagnetic resonance spectroscopy as well as magnetic measurements are reported. These macrocyclic complexes feature a simple and original design, and could find future uses as models for manganese catalase or as building blocks for the assembly of larger supramolecular architectures.


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