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RESEARCH ARTICLE
Contents Vol 73(6)

Allan White and Solvento/Aqua Complexes: ScIII Solvation

Eric J. Chan A , Simon A. Cotton B , Jack M. Harrowfield A C E , Brian W. Skelton A , Alexandre N. Sobolev A and Allan H. White A D
+ Author Affiliations
- Author Affiliations

A School of Molecular Sciences, The University of Western Australia, M310, 35 Stirling Highway, Perth, WA 6009, Australia.

B School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT, UK.

C Current address: Institut de Science et d’Ingenierie Supramoléculaires, Université de Strasbourg, 8, allée Gaspard Monge, 67083 Strasbourg, France.

D Deceased.

E Corresponding author. Email: harrowfield@unistra.fr

Australian Journal of Chemistry 73(6) 468-476 https://doi.org/10.1071/CH19130
Submitted: 21 March 2019  Accepted: 6 June 2019   Published: 4 July 2019

Abstract

Addition of various oxygen-donor ligands (L, all dipolar, aprotic solvents), to a solution of hydrated scandium picrate in weakly coordinating solvents (S), has yielded several crystalline adducts of the form Sc(pic)3(L)m(·nS) in which all ligands L are coordinated, subsequently characterised by a series of single crystal X-ray studies. For L = dmso, m = 3 and the picrate anions are all bound as phenoxide-O donor units, while for nmp, dma, tmp, and hmpa, m = 2 and one of the bound picrates becomes bidentate through phenoxide- and nitro-O donation. For L = ompa, m = 2 and two picrate ligands are bound through phenoxide-O while one is displaced from the primary coordination sphere. All complexes contain six-coordinate ScIII, confirming that this coordination number is a consequence of ligand bulk.


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