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RESEARCH ARTICLE
Contents Vol 70(5)

Rage Against Conformity: Ruthenium(ii) Bisterpyridine Complexes Respond to Crystal Engineering Instructions with Whelming Results*

Hasti Iranmanesh A , Kasun S. A. Arachchige A B , William A. Donald A , Niamh Kyriacou A , Chao Shen A , Jason R. Price C and Jonathon E. Beves A D E
+ Author Affiliations
- Author Affiliations

A School of Chemistry, The University of New South Wales, Sydney, NSW 2052, Australia.

B School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, Qld 4072, Australia.

C The Australian Synchrotron, 800 Blackburn Road, Clayton, Vic. 3168, Australia.

D Key State Laboratory for Coordination Chemistry, Nanjing University, Nanjing 210093, China.

E Corresponding author. Email: j.beves@unsw.edu.au

Australian Journal of Chemistry 70(5) 529-537 https://doi.org/10.1071/CH16620
Submitted: 2 November 2016  Accepted: 1 December 2016   Published: 19 January 2017

Abstract

Four heteroleptic ruthenium(ii) complexes of 4′-functionalised 2,2′:6′,2′′-terpyridine are reported, along with their solid-state single-crystal X-ray structures. The complexes feature complementary hydrogen-bond donor (phenol) and acceptor (pyridyl) groups designed to assemble into one-dimensional polymers. In one example, the system obeys the programmed instructions to form a one-dimensional, self-complementary hydrogen-bonded polymer. In one other example, a water-bridged hydrogen-bonded polymer is formed. In the remaining two structures, aryl–aryl interactions dominate the intermolecular interactions, and outweigh the contribution of intermolecular hydrogen bonding.


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