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RESEARCH ARTICLE
Contents Vol 70(1)

Direct Synthesis of Nitriles from Aldehydes and Hydroxylamine Hydrochloride Catalyzed by a HAP@AEPH2-SO3H Nanocatalyst

Samane Memar Masjed A , Batool Akhlaghinia A B , Monireh Zarghani A and Nasrin Razavi A
+ Author Affiliations
- Author Affiliations

A Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad 9177948974, Iran.

B Corresponding author. Email: akhlaghinia@um.ac.ir

Australian Journal of Chemistry 70(1) 33-43 https://doi.org/10.1071/CH16126
Submitted: 2 March 2016  Accepted: 15 May 2016   Published: 14 June 2016

Abstract

We describe an efficient method for the direct preparation of nitriles from aldehydes and hydroxylamine hydrochloride catalyzed by sulfonated nanohydroxyapatite functionalized by 2-aminoethyl dihydrogen phosphate (HAP@AEPH2-SO3H) as an eco-friendly and recyclable solid acid nanocatalyst. In this protocol the use of a solid acid nanocatalyst provides a green, useful, and rapid method for the preparation of nitriles in excellent yields. In addition, the notable feature of this methodolgy is that the synthesized nanocatalyst can be recovered and reused five times without any noticeable loss of efficiency.


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