Polyelectrolyte-Assisted Immobilization of Oil-Based Nanocapsules on Cotton Fabric
Yuwanda Iamphaojeen A , Avinash P. Manian B , Tom Wright B , Barnaby Caven B , Thomas Bechtold B and Punnama Siriphannon A C DA Functional Nanostructured Materials Laboratory, College of Nanotechnology, King Mongkut’s Institute of Technology Ladkrabang, Chalongkrung Road, Bangkok 10520, Thailand.
B Research Institute of Textile Chemistry and Textile Physics, University of Innsbruck, Höchsterstraße 73, A-6850, Dornbirn, Austria.
C Department of Chemistry, Faculty of Science, King Mongkut’s Institute of Technology Ladkrabang, Chalongkrung Road, Bangkok 10520, Thailand.
D Corresponding author. Email: punnama.si@kmitl.ac.th
Australian Journal of Chemistry 69(7) 811-816 https://doi.org/10.1071/CH15746
Submitted: 28 November 2015 Accepted: 31 January 2016 Published: 4 March 2016
Abstract
Poly(diallyldimethylammonium chloride)-encapsulated n-octadecane nanocapsules (PDDA-Oc-cap) were easily immobilized on cationized cotton at ambient temperature using poly(4-styrenesulfonic acid) (PSS) as a binder. The cationized cotton was first treated with 1–50 mM of PSS and then soaked in the PDDA-Oc-cap emulsion in order to obtain stepwise PSS/PDDA-Oc-cap coating layers on the cationized cotton (Cat-cot/PSS/PDDA-Oc-cap). The negative molecules of PSS binder spontaneously attached to the cationized cotton and then acted as negative sites for further immobilization of positively charged PDDA-Oc-cap via electrostatic interaction. Uniform globular particles of PDDA-Oc-cap were observed on the surfaces of Cat-cot/PSS/PDDA-Oc-cap samples in the field-emission scanning electron microscopy images. The positive zeta potential was obtained in the Cat-cot/PSS/PDDA-Oc-cap samples due to the deposition of the positively charged PDDA-Oc-cap on cotton fabric. In addition, the Cat-cot/PSS/PDDA-Oc-cap samples preferentially adsorbed anionic dye eosin B over cationic dye methylene blue. Higher PSS concentrations used in the treatment resulted in higher quantities of PDDA-Oc-cap immobilized on the fabrics, resulting in the concomitant increase of eosin B adsorption. These results suggested that the PSS-assisted immobilization was an efficient alternative method for textile finishing.
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