Rhodium(ii) Azavinyl Carbenes and their Recent Application to Organic Synthesis
Samantha C. Hockey A B and Luke C. Henderson A B C
+ Author Affiliations
- Author Affiliations
A Strategic Research Centre for Chemistry and Biotechnology, Deakin University, Pigdons Road, Geelong, Vic. 3216, Australia.
B Institute for Frontier Materials, Deakin University, Pigdons Road, Geelong, Vic. 3216, Australia.
C Corresponding author. Email: luke.henderson@deakin.edu.au
Australian Journal of Chemistry 68(12) 1796-1800 https://doi.org/10.1071/CH15363
Submitted: 19 June 2015 Accepted: 5 October 2015 Published: 21 October 2015
Abstract
This highlight solely focusses on the synthetic applications of azavinyl rhodium(II) carbenes derived from N-sulfonyl triazoles. An overview of their use in intermolecular reactions to form a variety of heterocycles is examined, in addition to intramolecular annulations and rearrangements.
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