Free Standard AU & NZ Shipping For All Book Orders Over $80!
Register      Login
Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
Shopping Cart: ( empty )
You are here: Home > Journals > CH > CH14290
RESEARCH ARTICLE
Contents Vol 68(3)

Two CoII Compounds Showing Interesting Magnetic Properties Modulated by Supramolecular Interactions

Xiao-Min Zhang A , Li-Na Meng A , Jian-Qiang Li A , Xue-Feng Feng A , Ming-Biao Luo A and Feng Luo A B
+ Author Affiliations
- Author Affiliations

A College of Biology, Chemistry and Material Science, East China Institute of Technology, Nanchang, Jiangxi 330013, China.

B Corresponding author. Email: ecitluofeng@163.com

Australian Journal of Chemistry 68(3) 433-440 https://doi.org/10.1071/CH14290
Submitted: 12 May 2014  Accepted: 6 June 2014   Published: 25 August 2014

Abstract

Two new CoII coordination compounds, namely Co[(cis-trans)-L](nip)·H2O (1) and Co[(cis-cis)-L](Hbtc)·2H2O (2) (L = N1,N4-di(pyridin-3-yl)terephthalamide, H2nip = 5-nitroisophthalic acid, H3btc = benzene-1,3,5-tricarboxylic acid), were synthesised hydrothermally and characterised by single crystal X-ray diffraction and direct current magnetic susceptibility measurement. Interestingly, the results disclose somewhat tuneable magnetic properties for compounds 1 and 2, mainly due to the distinct supramolecular interactions.


References

[1]  (a) R. E. P. Winpenny, Adv. Inorg. Chem. 2001, 52, 1.
         | 1:CAS:528:DC%2BD38XkvV2ltL8%3D&md5=125e7301a38e34933729000d9504a922CAS |
      (b) R. E. P. Winpenny, J. Chem. Soc., Dalton Trans. 2002, 1.
         | Crossref | GoogleScholarGoogle Scholar |

[2]  C. G. Efthymiou, C. P. Raptopoulou, A. Terzis, R. Boča, M. Korabic, J. Mrozinski, S. P. Perlepes, E. G. Bakalbassis, Eur. J. Inorg. Chem. 2006, 2006, 2236.
         | Crossref | GoogleScholarGoogle Scholar |

[3]  X. M. Zhang, J. Q. Li, S. J. Liu, M. B. Luo, W. Y. Xu, F. Luo, CrystEngComm 2014, 16, 2570.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC2cXjsVKjsrY%3D&md5=a153d8920084ee67b14f9909a8a8fbd0CAS |

[4]  S. Mukhopadhyay, S. K. Mandal, S. Bhaduri, W. H. Armstrong, Chem. Rev. 2004, 104, 3981.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2cXnt12iur8%3D&md5=17228c500538a206d0ad8676c5bfc056CAS | 15352784PubMed |

[5]  (a) R. Sessoli, H. L. Tsai, A. R. Schake, S. Wang, J. B. Vincent, K. Folting, D. Gatteschi, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc. 1993, 115, 1804.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2cXptlymtg%3D%3D&md5=40205a21298518b65526618fb7e82d0eCAS |
      (b) R. Sessoli, D. Gatteschi, A. Caneschi, M. A. Novak, Nature 1993, 365, 141.
         | Crossref | GoogleScholarGoogle Scholar |

[6]  (a) G. Christou, D. Gatteschi, D. N. Hendrickson, R. Sessoli, MRS Bull. 2000, 25, 66.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3cXosl2qurk%3D&md5=ad45fbf067954b74e1e7b04672e41341CAS |
      (b) D. Gatteschi, R. Sessoli, Angew. Chem. Int. Ed. 2003, 42, 268.
         | Crossref | GoogleScholarGoogle Scholar |

[7]  G. Christou, Polyhedron 2005, 24, 2065.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2MXhtFymsbjO&md5=51bf1793843f63c1f5b3e07015e83f1dCAS |

[8]  (a) M. H. Zeng, M. X. Yao, H. Liang, W. X. Zhang, X. M. Chen, Angew. Chem. Int. Ed. 2007, 46, 1832.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXksVWgtrY%3D&md5=236b66b50f4a175dd7a93a0a3f409cd4CAS |
      (b) Q. Chen, M. H. Zeng, Y. L. Zhou, H. H. Zou, M. Kurmoo, Chem. Mater. 2010, 22, 2114.
         | Crossref | GoogleScholarGoogle Scholar |

[9]  (a) G. Christou, Polyhedron 2005, 24, 2065.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2MXhtFymsbjO&md5=51bf1793843f63c1f5b3e07015e83f1dCAS |
      (b) P. L. Feng, C. Koo, J. J. Henderson, P. Manning, M. Nakano, E. D. Barco, S. Hill, D. N. Hendrickson, Inorg. Chem. 2009, 48, 3480.
         | Crossref | GoogleScholarGoogle Scholar |

[10]     (a) D. Gatteschi, O. Kahn, J. S. Miller, F. Palacio, Magnetic Molecular Materials 1991 (Kluwer Academic: Dordrecht).
      (b) M. Verdaguer, Polyhedron 2001, 20, 1115.
         | Crossref | GoogleScholarGoogle Scholar |
      (c) E. C. Miralles, Polyhedron 2003, 22, 1725.
         | Crossref | GoogleScholarGoogle Scholar |

[11]  M. Kurmoo, H. Kumagai, K. W. Chapman, C. J. Kepert, Chem. Commun. 2005, 3012.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2MXlt12mtrw%3D&md5=5bbb1c8425a169417ea7c4f60004ef86CAS |

[12]  (a) G. J. Halder, C. J. Kepert, B. Moubaraki, K. S. Murray, J. D. Cashion, Science 2002, 298, 1762.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD38XovFKmsrs%3D&md5=b76c9131650d62ab8f7978e3602f8722CAS | 12459583PubMed |
      (b) X. N. Cheng, W. X. Zhang, Y. Y. Lin, Y. Z. Zheng, X. M. Chen, Adv. Mater. 2007, 19, 1494.
         | Crossref | GoogleScholarGoogle Scholar |

[13]  (a) H. L. Sun, Z. M. Wang, S. Gao, Coord. Chem. Rev. 2010, 254, 1081.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3cXivVOqu7g%3D&md5=f8516381574b010de07ce4ee44c35324CAS |
      (b) L. Bogani, A. Vindigni, R. Sessoli, D. J. Gatteschi, Mater. Chem. 2008, 18, 4750.
         | Crossref | GoogleScholarGoogle Scholar |

[14]  (a) E. Coronado, K. R. Dunbar, Inorg. Chem. 2009, 48, 3293.(Special issue for the Forum on Molecular Magnetism: The Role of Inorganic Chemistry).
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1MXktVGls7o%3D&md5=99fb747d19279333dad837419a6799e0CAS | 19361234PubMed |
      (b) T. Yamada, K. Otsubo, R. Makiura, H. Kitagawa, Chem. Soc. Rev. 2013, 42, 6655.
         | Crossref | GoogleScholarGoogle Scholar |
      (c) P. Dechambenoit, J. R. Long, Chem. Soc. Rev. 2011, 40, 3249.
         | Crossref | GoogleScholarGoogle Scholar |
      (d) W. L. Leong, J. J. Vittal, Chem. Rev. 2011, 111, 688.
         | Crossref | GoogleScholarGoogle Scholar |
      (e) Z. M. Wang, K. L. Hu, S. Gao, H. Kobayashi, Adv. Mater. 2010, 22, 1526.
         | Crossref | GoogleScholarGoogle Scholar |
      (f) T. Hang, W. Zhang, H. Y. Ye, R. G. Xiong, Chem. Soc. Rev. 2011, 40, 3577.
         | Crossref | GoogleScholarGoogle Scholar |

[15]  M. Kurmoo, Chem. Soc. Rev. 2009, 38, 1353.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1MXkvVamu7s%3D&md5=385569abfd18a70d569f1978d993e1a4CAS | 19384442PubMed |

[16]  M. Kurmoo, H. Kumagai, M. Akita-Tanaka, K. Inoue, S. Takagi, Inorg. Chem. 2006, 45, 1627.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD28XksFSitg%3D%3D&md5=78d3600ee658f633a758af2760c337f0CAS | 16471975PubMed |

[17]  (a) M. Wriedt, A. A. Yakovenko, G. J. Halder, A. V. Prosvirin, K. R. Dunbar, H. C. Zhou, J. Am. Chem. Soc. 2013, 135, 4040.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3sXis1Sktrw%3D&md5=8e8d539fdb29a7be407870ea446892acCAS | 23414430PubMed |
      (b) S. Mohapatra, B. Rajeswaran, A. Chakraborty, A. Sundaresan, T. K. Maji, Chem. Mater. 2013, 25, 1673.
         | Crossref | GoogleScholarGoogle Scholar |
      (c) J. Ferrando-Soria, R. Ruiz-García, J. Cano, S. E. Stiriba, J. Vallejo, I. Castro, M. Julve, F. Lloret, P. Amorós, J. Pasán, C. Ruiz-Pérez, Y. Journaux, E. Pardo, Chem. – Eur. J. 2012, 18, 1608.
         | Crossref | GoogleScholarGoogle Scholar |

[18]  N. Hoshino, F. Iijima, G. N. Newton, N. Yoshida, T. Shiga, H. Nojiri, A. Nakao, R. Kumai, Y. Murakami, H. Oshio, Nat. Chem. 2012, 4, 921.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC38XhtlGjs7vL&md5=654ac2fa3a94abb329a731673f462366CAS | 23089867PubMed |

[19]  O. Kahn, Molecular Magnetism 1993 (VCH: New York, NY), p. 38.

[20]  S. O. H. Gutschke, D. J. Price, A. K. Powell, P. T. Wood, Angew. Chem. Int. Ed. 1999, 38, 1088.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK1MXivFCmtLo%3D&md5=c13cc1da84d336a7369753da4a004c2cCAS |

[21]  (a) R. Baggio, M. T. Garland, Y. Moreno, O. Péna, M. Perec, E. Spodine, J. Chem. Soc., Dalton Trans. 2000, 2061.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3cXktlCns7Y%3D&md5=245d5df1afcf5d2491453536e7fb92d8CAS |
      (b) Y. C. Liang, M. C. Hong, W. P. Su, R. Cao, W. J. Zhang, Inorg. Chem. 2001, 40, 4574.
         | Crossref | GoogleScholarGoogle Scholar |
      (c) J. P. Costes, G. Novitchi, S. Shova, F. Dahan, B. Donnadieu, J. P. Tuchagues, Inorg. Chem. 2004, 43, 7792.
         | Crossref | GoogleScholarGoogle Scholar |
      (d) S. C. Xiang, S. M. Hu, T. L. Sheng, J. S. Chen, X. T. Wu, Chem. – Eur. J. 2009, 15, 12496.
         | Crossref | GoogleScholarGoogle Scholar |

[22]  X. Q. Zhao, P. Cui, B. Zhao, W. Shi, P. Cheng, Dalton Trans. 2011, 40, 805.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXjslWgtw%3D%3D&md5=bf15ded831b3c26840fd554c2ab5a4b7CAS | 21152624PubMed |

[23]  (a) F. Luo, Y. X. Che, J. M. Zheng, Cryst. Growth Des. 2006, 6, 2432.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD28XpvVChs7w%3D&md5=a9550839d2c2222ef45596c79511c117CAS |
      (b) F. Luo, D. X. Hu, L. Xue, Y. X. Che, J. M. Zheng, Cryst. Growth Des. 2007, 7, 851.
         | Crossref | GoogleScholarGoogle Scholar |
      (c) F. Luo, Y. T. Yang, Y. X. Che, J. M. Zheng, CrystEngComm 2008, 10, 1613.
         | Crossref | GoogleScholarGoogle Scholar |

[24]  (a) V. Chandrasekhar, B. M. Pandian, R. Azhakar, J. J. Vittal, R. Clérac, Inorg. Chem. 2009, 48, 1148.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1MXjtVensA%3D%3D&md5=d73631d9919422a085a90192e02fabfdCAS | 19128155PubMed |
      (b) V. Chandrasekhar, B. M. Pandian, R. Azhakar, J. J. Vittal, R. Clérac, Inorg. Chem. 2007, 46, 5140.
         | Crossref | GoogleScholarGoogle Scholar |

[25]  (a) F. Luo, J. M. Zheng, S. R. Batten, Chem. Commun. 2007, 36, 3744.
         | Crossref | GoogleScholarGoogle Scholar |
      (b) F. Luo, Y. X. Che, J. M. Zheng, Microporous Mesoporous Mater. 2009, 117, 486.
         | Crossref | GoogleScholarGoogle Scholar |
      (c) N. L. S. Yue, D. J. Eisler, M. C. Jennings, Inorg. Chem. 2004, 43, 7671.
         | Crossref | GoogleScholarGoogle Scholar |
      (d) Z. Q. Qin, M. C. Jennings, R. J. Puddephatt, Inorg. Chem. 2003, 42, 1956.
         | Crossref | GoogleScholarGoogle Scholar |
      (e) F. Luo, M. S. Wang, M. B. Luo, G. M. Sun, Y. M. Song, P. X. Li, G. C. Guo, Chem. Commun. 2012, 48, 5989.
         | Crossref | GoogleScholarGoogle Scholar |
      (f) F. Luo, Z. Z. Yuan, X. F. Feng, S. R. Batten, J. Q. Li, M. B. Luo, S. J. Liu, W. Y. Xu, G. M. Sun, Y. M. Song, H. X. Huang, X. Z. Tian, Cryst. Growth Des. 2012, 12, 3392.
         | Crossref | GoogleScholarGoogle Scholar |
      (g) G. M. Sun, Y. M. Song, Y. Liu, X. Z. Tian, H. X. Huang, Y. Zhu, Z. J. Yuan, X. F. Feng, M. B. Luo, S. J. Liu, W. Y. Xu, F. Luo, CrystEngComm 2012, 14, 5714.
         | Crossref | GoogleScholarGoogle Scholar |
      (h) G. M. Sun, H. X. Huang, X. Z. Tian, Y. M. Song, Y. Zhu, Z. J. Yuan, W. Y. Xu, M. B. Luo, S. J. Liu, X. F. Feng, F. Luo, CrystEngComm 2012, 14, 6182.
         | Crossref | GoogleScholarGoogle Scholar |
      (i) G. M. Sun, F. Luo, Y. M. Song, Y. Liu, X. Z. Tian, H. X. Huang, Y. Zhu, Z. J. Yuan, X. F. Feng, M. B. Luo, S. J. Liu, W. Y. Xu, Dalton Trans. 2012, 41, 11559.
         | Crossref | GoogleScholarGoogle Scholar |

[26]  G. Sheldrick, SHELX-2014 2014 (Institute of Inorganic Chemistry: Göttingen). Available at http://shelx.uni-ac.gwdg.de/SHELX/